Keywords
polydentate ligands
metal-silyl complexes
hydrogenation
hydrosilylation
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Abstract
The chemistry of transition metal complexes with monoanionic bidentate ligands k2-Si,L and/or tridentate k3-Si,L2—where Si represents a silyl group and L ligands with neutral s-donor groups—has gained increasing interest in recent years. This review highlights the advances achieved through the application of these complexes as catalysts in essential processes, such as the hydrogenation and hydrosilylation of unsaturated molecules.
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