Abstract
Chiral nanographenes represent a new type of material capable of emitting circularly polarized light, positioning them as potential candidates in chiral optoelectronics. This work selects some of the latest advances in the synthesis and design of chiral NGs, highlighting molecular strategies that enable modulation of CPL response. Additionally, future perspectives toward optimizing CPL efficiency and the potential of these entities in advanced technological applications are discussed.
References
V. S. Iyer, M. Wehmeier, J. D. Brand, M. A. Keegstra, K. Mullen, Angew. Chem., Int. Ed. 1997, 36, 1604-1607, https://doi.org/10.1002/anie.199716041.
D. Reger, P. Haines, K. Y. Amsharov, J. A. Schmidt, T. Ullrich, S. Bonisch, F. Hampel, A. Gorling, J. Nelson, K. E. Jelfs, D. M.Guldi, N. Jux, Angew. Chem., Int. Ed. 2021, 60, 18073-18081, https://doi.org/10.1002/anie.202103253.
C. M. Cruz, S. Castro-Fernandez, E. Macoas, J. M. Cuerva, A. G. Campana, Angew. Chem., Int. Ed. 2018, 57, 14782-14786, https://doi.org/10.1002/anie.201808178.
D. Reger, P. Haines, F. W. Heinemann, D. M. Guldi, N. Jux, Angew. Chem., Int. Ed. 2018, 57, 5938-5942, https://doi.org/10.1002/anie.201800585.
J. Lion-Villar, J. M. Fernandez-Garcia, S. Medina Rivero, J. Perles, S. Wu, D. Aranda, J. Wu, S. Seki, J. Casado, N. Martin, Nat.Chem. 2025, 17, 1099-1106, https://doi.org/10.1038/s41557-025-01810-2.
M. M. Martin, F. Hampel, N. Jux, Chem. - Eur. J. 2020, 26, 10210-10212, https://doi.org/10.1002/chem.202001471.
F. Morita, Y. Kishida, Y. Sato, H. Sugiyama, M. Abekura, J. Nogami, N. Toriumi, Y. Nagashima, T. Kinoshita, G. Fukuhara, M. Uchiyama, H. Uekusa, K. Tanaka, Nat. Synth. 2024, 3, 774-786, https://doi.org/10.1038/s44160-024-00527-3.
Z. Qiu, C. W. Ju, L. Frederic, Y. Hu, D. Schollmeyer, G. Pieters, K. Mullen, A. Narita, J. Am. Chem. Soc. 2021, 143, 4661-4667, https://doi.org/10.1021/jacs.0c13197.
Y. Ma, L. Zhou, J. Tan, W. Sun, Y. Zou, Y. Hu, Adv. Optical Mater 2025, 13, 2402446, https://doi.org/10.1002/adom.202402446.
R. Yamano, Y. Shibata, K. Tanaka, Chem. – Eur. J. 2018, 24, 6364-6370, https://doi.org/10.1002/chem.201706008.
G. Huo, W. Xu, J. Hu, Y. Han, W. Fan, W. Wang, Z. Sun, H. Yang, J. Wu, Angew. Chem., Int. Ed. 2025, 64, e202416707, https://doi.org/10.1002/anie.202416707.
W. Niu, Y. Fu, Z.-L. Qiu, C. J. Schurmann, S. Obermann, F. Liu, A. A. Popov, H. Komber, J. Ma, X. Feng, J. Am. Chem. Soc. 2023, 145, 26824-26832, https://doi.org/10.1021/jacs.3c01088.
P. Izquierdo-Garcia, J. M. Fernandez-Garcia, S. Medina Rivero, M. Šamal, J. Rybaček, L. Bednarova, S. Ramirez-Barroso, F. J. Ramirez, R. Rodriguez, J. Perles, D. Garcia-Fresnadillo, J. Crassous, J. Casado, I. G. Stara, N. Martin, J. Am. Chem. Soc. 2023, 145, 11599-11610, https://doi.org/10.1021/jacs.3c01088.
Y. Wada, K. Shinohara, T. Ikai, Chem. Commun. 2019, 55, 11386-11389, https://doi.org/10.1039/C9CC06025A.
M. Buendia, J. M. Fernandez-Garcia, J. Perles, S. Filippone, N. Martin, Nat. Synth. 2024, 3, 545-553, https://doi.org/10.1038/s44160-024-00484-x.
C. M. Cruz, I. R. Marquez, I. F. A. Mariz, V. Blanco, C. Sanchez-Sanchez, J. M. Sobrado, J. A. Martin-Gago, J. M. Cuerva, E. Macoas, A. G. Campana, Chem. Sci. 2018, 9, 3917-3924, https://doi.org/10.1039/C8SC00427G.
V. Kumar, G. Venugopal, A. B. Jadhav, S. D. Dongre, R. Gonnade, J. Kumar, P. C. Ruer, B. Hupp, A. Steffen, S. S. Babu, Angew. Chem., Int. Ed. 2025, 64, https://doi.org/10.1002/anie.202422125.
P. Izquierdo-Garcia, J. M. Fernandez-Garcia, J. Perles, N. Martin, J. Am. Chem. Soc. 2024, 146, 34943-34949, https://doi.org/10.1021/jacs.4c14544.
S. Li, R. Li, Y. K. Zhang, S. Wang, B. Ma, B. Zhang, P. An, Chem. Sci. 2023, 14, 3286-3292, https://doi.org/10.1039/D2SC06244E.
W. Niu, Y. Fu, Q. Deng, Z. L. Qiu, F. Liu, A. A. Popov, H. Komber, J. Ma, X. Feng, Angew. Chem., Int. Ed. 2024, 63, e202319874, https://doi.org/10.1002/anie.202319874.
S. Miguez-Lago, I. F. A. Mariz, M. A. Medel, J. M. Cuerva, E. Macoas, C. M. Cruz, A. G. Campana, Chem. Sci. 2022, 13,10267-10272, https://doi.org/10.1039/D2SC03452B.
X. Y. Wang, J. Bai, Y. J. Shen, Z. A. Li, H. Y. Gong, Angew. Chem., Int. Ed. 2025, 64, e202417745, https://doi.org/10.1002/anie.202417745.
K.-L. Zhu, Z.-A. Li, J. Liang, K.-L. Zou, Y.-J. Shen, H.-Y. Gong, K. Zhu, Z. Li, J. Liang, K. Zou, Y. Shen, H. Gong, Angew. Chem., Int. Ed. 2024, e202409713, https://doi.org/10.1002/anie.202409713.
Y.-J. Shen, L.-J. Peng, L.-N. Diao, N.-T. Yao, W.-K. Chen, Y. Yang, M. Qiu, W.-X. Zhu, X. Li, X.-Y. Wang, H.-Y. Gong, Org. Lett. 2024, 26, 7279-7284, https://doi.org/10.1021/acs.orglett.4c02093.
C. M. Cruz, I. R. Marquez, S. Castro-Fernandez, J. M. Cuerva, E. Macoas, A. G. Campana, Angew. Chem., Int. Ed. 2019, 58, 8068-8072, https://doi.org/10.1002/anie.201902529.
R. G. Uceda, C. M. Cruz, S. Miguez-Lago, L. A. de Cienfuegos, G. Longhi, D. A. Pelta, P. Novoa, A. J. Mota, J. M. Cuerva, D. Miguel, Angew. Chem., Int. Ed. 2024, 63, e202316696, https://doi.org/10.1002/anie.202316696.
R. G. Uceda, A. Gijon, S. Miguez-Lago, C. M. Cruz, L. Alvarez de Cienfuegos, A. J. Mota, D. Miguel, J. M. Cuerva, ChemPhotoChem 2025, 9, e202500079, https://doi.org/10.1002/cptc.202500079.
R. G. Uceda, A. Gijon, S. Miguez-Lago, C. M. Cruz, V. Blanco, F. Fernandez-Alvarez, L. Alvarez de Cienfuegos, M. Molina-Solana, J. Gomez-Romero, D. Miguel, A. J. Mota, J. M. Cuerva, Angew. Chem., Int. Ed. 2024, 63, e202409998, https://doi.org/10.1002/ange.202409998.

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Copyright (c) 2025 Anales de Química de la RSEQ

